Aldrich

Triethylsilane

467448 -

97%

DOWNLOAD MSDS (PDF)

Synonym: NSC 93579, Triethylhydrosilane, Triethylsilicon hydride

  • CAS Number: 617-86-7

  • Linear Formula: (C2H5)3SiH

  • Molecular Weight: 116.28

  • Beilstein Registry Number: 1098278

  • EC Number: 210-535-3

  • MDL number: MFCD00009018

  • PubChem Substance ID: 24870410

Properties

Related CategoriesReduction, Silanes, Synthetic Reagents
assay97%
refractive indexn20/D 1.412(lit.)
bp107-108 °C(lit.)
density0.728 g/mL at 25 °C(lit.)

Description

Packaging

25, 100 mL in Sure/Seal™

Application

Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5

Catalyst reactivation after catalyst polymerization of styrene6

Studies involving the prediction of organosilicon flash points7

Price and Availability

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Documents

Certificate of Analysis

Certificate of Origin

FT-IR Condensed Phase
FT-IR Raman
FT-NMR
Structure Search
Pressure-Temperature Nomograph
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Safety Information

SymbolGHS02  GHS02
Signal wordDanger
Hazard statementsH225-H412
Precautionary statementsP210-P273
Personal Protective EquipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard CodesF
Risk Statements11
Safety Statements9-16-29-33
RIDADRUN 1993 3/PG 2
WGK Germany1
Flash Point(F)26.6 °F
Flash Point(C)-3 °C
Technical information & documentation associated with this product is available in the Safety & Documentation tab.

References

1. S. Chowdhury, et al., Bioorg. Med. Chem. Lett. 21, 3676-3681, (2011)

2. J. V. Crivello, J. Polym. Sci., A: Polym. Chem. 49, 2147-2154, (2011)

3. J. V. Crivello and J. L. Lee, J. Polym. Sci., A: Polym. Chem. 48, 4484-4495, (2010)

4. S. Sato, et al., Chem. Lett. 39, 1319-1320, (2010)

5. W. Li, et al., Angew. Chem. Int. Ed. Engl. 49, 8712-8716, (2010)

6. G. W. Theaker, et al., Macromolecules 44, 1393-1404, (2011)

7. C. Chen, et al., Ind. and Eng. Chem. 49, 12702-12708, (2010)

Merck 14,10372

Beil. 4,IV,3895

Fieser 1,1218 / Fieser 2,433 / Fieser 3,304 / Fieser 4,530 / Fieser 5,694 / Fieser 15,338 / Fieser 16,356 / Fieser 17,367

Aldrich MSDS 1, 1755:B / Corp MSDS 1 (2), 3437:A / FT-IR 2 (3), 4338:D / FT-IR 1 (2), 1098:C / FT-NMR 1 (3), 629:C / NMR-Reference 2 (2), 983:B / RegBook 1 (2), 2951:C / Structure Index 1, 467:E:1 / Vapor Phase 3, 1622:B


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